Ferroelectrets

Ferroelectrets

Fig. 1: SEM-image of the cross section of a cellular PP-film (top) and charge distribution in the film (bottom) [1]
Fig. 1: SEM-image of the cross section of a cellular PP-film (top) and charge distribution in the film (bottom) [1]

These new electrets with piezoelectric properties consist of an internally charged cellular dielectric, typically a polymer such as polypropylene (PP), with voids of heights in the order of a few µm and lateral dimensions of several tens of µm. Such voids can be generated by biaxially stretching a polymer film filled with small particles. During the stretching, microcracks form around the particles and develop into flat voids. A cross section of a cellular PP sample is shown in Fig. 1 (top) [1]. The voids can be enlarged in the thickness direction of the film by a pressure treatment, consisting of an increase of the pressure of the surrounding gas, such that gas penetrates into the voided structure. A subsequent pressure release inflates the material.

Fig. 2: Quasistatic d33-coefficients for corona charged cellular fluoropolymer and PP films as function of time at 90°C annealing temperature [2]
Fig. 2: Quasistatic d33-coefficients for corona charged cellular fluoropolymer and PP films as function of time at 90°C annealing temperature [2]

Charging of such a sample is achieved by exposure of one of its surfaces to a corona discharge. The deposited charges together with their counter charges on a back electrode generate a high internal field which causes breakdowns in the voids and thus deposition of charges of opposite sign on the upper and lower void surfaces, respectively. Finally, the sample is metallized on its two surfaces. The cross section of a charged and metallized ferroelectret film is shown in a schematic view in Fig. 1 (bottom). The films now exhibit large piezoelectric d33-coefficients which are very stable at room temperature. However, at temperatures above 50°C the charges and thus the d33-coefficients are significantly reduced in the PP samples.

Recently, the thermal stability has been considerably improved with structured fluoropolymer samples [2]. These samples consist of layers of polytetrafluoroethylene (PTFE) and fluoroethylenepropylene (FEP) which are fused at high temperature such that small interfacial gas voids are formed between the layers. After charging and annealing, the fused multilayer films show large d33-coefficients thermally stable up to 90°C, as shown in Fig. 2.

Comparison of piezoelectric properties

The piezoelectric properties of such ferroelectrets have been analyzed by a simple model and experimental results can be explained by such calculations [3,4]. Typical d33-coefficients for PP and PTFE/FEP ferroelectrets are compared in Table 1 with values for polyvinylidenefluoride (PVDF) and the conventional piezoelectric materials quartz and lead circonate titanate (PZT-5). The huge d33-coefficients of the ferroelectrets are noteworthy. Since the ferroelectrets and PVDF are polymers, they have certain other properties such as mechanical softness and flexibility which distinguish them from the conventional piezoelectrics.

Piezoelectric material d33 (pC/N)
Quartz 2.3 (d11)
PZT-5 370
PVDF 20
Cellular PP (expanded) 600
Cellular PTFE/FEP sandwiches 300

Literature

  • [1] J. Hillenbrand and G. M. Sessler, “Piezoelectricity in Cellular Electret Films”, IEEE Trans. Dielectrics and Electrical Insulation 7, 537 – 542 (2000).
  • [2] X. Zhang, J. Hillenbrand, and G. M. Sessler, “Ferroelectrets with improved thermal stability made from fused fluorocarbon layers”, J. Appl. Phys. 101, 054114 (2007).
  • [3] G. M. Sessler and J. Hillenbrand, “Electromechanical Response of Cellular
  • Electret Films”, Appl. Phys. Letters 75, 3405 – 3407 (1999).
  • [4] J. Hillenbrand, G. M. Sessler, and X. Zhang, “Verification of a model for the piezoelectric d33-coefficient of cellular electret films”, J. Appl. Phys. 98, 064105 (2005).